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Beilstein J. Org. Chem. 2017, 13, 1999–2009, doi:10.3762/bjoc.13.196
Graphical Abstract
Figure 1: (a) Structures of cell-membrane glycerophospholpids with a common asymmetric 1,2-diacyl-sn-glycerol...
Scheme 1: The four 1,2-dipalmitoyl-sn-glycerols 1–4 examined in this study.
Figure 2: 1H NMR spectra of 1,2-dipalmitin (3) in CDCl3 after partial isomerization into the 1,3-isomer. (a) ...
Figure 3: Fractional populations (%) of the three staggered conformers around the sn-1,2 C–C single bond in 1...
Scheme 2: Structures of glycerophospholipids with a common structural skeleton of 1,2-dipalmitoyl-sn-glycerol...
Figure 4: Partial 1H NMR spectrum of 4 in a mixture of CDCl3 and methanol-d4 (C/M = 10:1, v/v).
Figure 5: Linear relation between the helical disparity (%) and gt(+) population (%) as observed for the heli...
Figure 6: An empirical diagram showing helical conformational properties around 1,2-diacyl moiety in asymmetr...
Scheme 3: Chirally 2H-labelled tripalmitins (1S)- and (1R)-1-[2H]-1 [23].
Beilstein J. Org. Chem. 2014, 10, 1504–1512, doi:10.3762/bjoc.10.155
Figure 1: Structure of bis(β-lactosyl)-[60]fullerene (bis-Lac-C60).
Scheme 1: Synthesis of bis-Lac-C60. Reagents and conditions: (a) 6-chloro-1-hexanol, TMSOTf, CH2Cl2, −40 °C, ...
Figure 2: Precipitation assay of bis-Lac-C60 colloidal solution. The tubes were allowed to stand for 10 min a...
Figure 3: Schematic image for the quantitative analysis of ricin protein in the colloidal suspension of bis-L...
Figure 4: A modified procedure for the rapid detection and the efficient decontamination of ricin and ricin-l...